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Compounds · Monoterpenes · Terpenoid pathway

Terpinolene

Lightly sweet, piney, with a slight floral note. Softer than the other monoterpenes.

CAS
586-62-9
Formula
C10H16
Molar mass
136.23
Odour threshold
200 ppbin water
Boiling point
≈ 186 °C at atmospheric pressure
Volatility
150 °C290 °C
Threshold
most potentleast potent

The two axes are 46 points apart. Volatility tells you whether the compound leaves a surface early or late; the threshold tells you how much of it the nose needs before it notices. When the two sit this far apart, they explain things the percentages on an analysis cannot explain on their own.

Must be declared on the label

This compound was added by Regulation (EU) 2023/1545 to the list of allergens that must be declared individually on cosmetic labels in the European Union. Name to use on the label: TERPINOLENE.

The declaration threshold is 0.001% in leave-on products and 0.01% in rinse-off products. This is an EU requirement — see the regulations page for why it matters beyond the EU. This is not legal advice.

Where it comes from

Biosynthetic pathway: Terpenoid pathway — plants build them from identical five-carbon blocks.

About the threshold figure

High, similar to limonene.

Published thresholds differ by several orders of magnitude, because of differences in measuring method, sample purity and panel. The figure here is an order of magnitude for relative comparison, not a measurement. We give it only for compounds where the literature broadly agrees — 52 of the 106 compounds in the library. The rest are left blank rather than guessed.

Why it sits where it does

Its double bond outside the ring makes the molecule less symmetrical, and that slightly lowers its vapour pressure compared with limonene.

Where else you meet it

Pine, rosemary, apple, and many cannabis varieties. Usually present at under a few per cent, but it contributes clearly to the sweet note.