When a distillation run ends, the separator holds two layers: essential oil and water. For most oils the top layer is the oil, and it is drawn off.
Not always. Clove, cinnamon bark and wintergreen have oils heavier than water, so they sit in the bottom layer — the distiller has to know this in advance so as not to draw off the wrong one.
The water layer, whether on top or underneath, was poured away for most of this craft’s history.
It is not plain water
That water layer is called hydrosol or floral water. It contains the molecules that dissolve in water and that the essential oil does not retain.
This is the important point: a hydrosol is not diluted essential oil. It is a different fraction, with a different composition.
Essential oil keeps the water-repellent molecules — hydrocarbons, esters, most terpenes. Hydrosol keeps the more polar molecules, rich in hydroxyl and acid groups.
So for some species, the hydrosol smells quite different from the oil of the same batch.
Three notable cases
Rose. Rose water has a history centuries longer than rose oil. The Persians distilled roses to obtain the water, and the oil was at first just a film floating on top that nobody yet knew how to use.
Orange blossom. Orange blossom water is clearly different from neroli, and in Mediterranean cooking it is used more than the oil.
Cajuput and mint. Their hydrosols are lighter and clearer, less sharp.
Why few people talk about it
Hydrosol is very low in concentration, short-lived because it contains water and so microorganisms can live in it, and of low commercial value compared with essential oil.
For a producer, treating and bottling hydrosol is laborious and the margin thin. Pouring it away is simpler.
Worth knowing when buying
Not everything called rose water is a hydrosol. Many products on the market are distilled water with fragrance added, of completely different origin.
How to tell: real hydrosol is usually slightly cloudy or has a very thin film, has a short shelf life, and needs cool storage. A product that is crystal clear, with a three-year shelf life and kept at room temperature, is almost certainly not a hydrosol.
Ask the same question as with essential oil: which lot, distilled when, from what raw material.